Smart Responsive Luminescent Aptamer-Functionalized Covalent Organic Framework Hydrogel for High-Resolution...

Covalent organic frameworks (COFs) have been proposed as alternative candidates for "smart" materials due to their ordered π-columnar structures. However, it remains a challenge to develop external-stimuli-responsive luminescent COFs for confidential information protection. Here, we have designed and synthesized a water-dispersible and smart responsive luminescent carboxymethyl cellulose-COF hydrogel encapsulated 5-(dimethylamino)-N,N-bis (pyridin-2-ylmethyl) napthalene-1-sulfonamide, named CMC-COF-LZU1⊃DPYNS, for latent fingerprint imaging and encryption. We show that the fluorescence of CMC-COF-LZU1⊃DPYNS is reversibly switchable upon addition of Cu²⁺/H₂O. This effect endows potential applications of tunable luminescent COFs based hydrogel as an invisible security probe for imaging, recording, storage, and security of latent fingerprint information. It is shown that the latent fingerprint information incubated by the aptamer-functionalized CMC-COF-LZU1⊃DPYNS hydrogel is invisible in the presence of Cu²⁺, but three levels of fingerprint features with high-resolution patterns could be readable upon addition of H₂O under UV light. The design strategy provides a promising platform for the development of smart responsive luminescent COFs and their detection and protection of valuable latent fingerprint information.