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Updated: Jan 4, 2026

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Highly Dense Packing of Chromophoric Linkers Achievable in a Pyrene-Based Metal-Organic Framework for Photoelectric
Jian-Hua Qin1, Ya-Dan Huang1,2, Ying Zhao1
1College of Chemistry and Chemical Engineering, Henan Key Laboratory of Function-Oriented Porous Materials , Luoyang Normal University , Luoyang 471934 , P. R. China.
Abstract:
Highly dense packing of chromophoric linkers is achieved in a novel pyrene-based metal-organic framework (MOF), [Zn(TBAPy)1/2(H2O)2], induced by an ionic liquid. This MOF displays a quick response to visible-light irradiation (photocurrent density of up to 4.492 μA cm-2) and is capable of repetitive on-off photocurrent switching with a large on-off ratio (37.55).
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