Unexpected dynamical effects change the lambda-doublet propensity in the tunneling region for the O(³P) + H₂ reaction

One of the most relevant features of the O(³P) + H₂ reaction is that it occurs on two different potential energy surfaces (PESs) of symmetries A' and A'' that correlate reactants and products. The respective saddle points, which correspond to a collinear arrangement, are the same for both PESs, whilst the barrier height rises more abruptly on the ³A' PES than on the ³A'' PES. Accordingly, the reactivity on the ³A'' PES should be always higher than on the ³A' PES. In this work, we present accurate quantum-scattering calculations showing that this is not always the case for rotationless reactants, where dynamical factors near the reaction threshold cause the ³A' PES to dominate at energies around the barrier. Further calculation of cross sections and Λ-doublet populations has allowed us to establish how the reaction mechanism changes from the deep tunneling regime to hyperthermal energies.