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Related Concept Videos

Precipitation Gravimetry01:03

Precipitation Gravimetry

12.8K
Precipitation gravimetry is based on converting an analyte into a sparingly soluble precipitate, which is separated by filtration and weighed. An ideal precipitate should be pure, insoluble, of known composition, and easily filtered from the reaction mixture.
In determining nickel by gravimetric analysis, a precipitant of ethanolic dimethylglyoxime is added to a hot nickel salt solution. This is quickly followed by the dropwise addition of dilute ammonia solution until precipitation occurs. A...
12.8K
Precipitation and Co-precipitation01:17

Precipitation and Co-precipitation

4.0K
Precipitation and coprecipitation methods can be used to separate a mixture of ions in a solution. In qualitative inorganic analysis, ions that form sparingly soluble precipitates with the same reagent are separated based on the differences in solubility products. For example, consider the separation of Cu(II) and Fe(II) ions by precipitation as insoluble sulfides. First, copper(II) sulfide is precipitated by the addition of acidic H2S, where the dissociation of H2S is suppressed. Adding H2S...
4.0K
Precipitation Processes01:12

Precipitation Processes

4.5K
The experimental conditions in a gravimetric analysis should be optimized to maximize the particle size and purity of the obtained precipitate. Ideally, the concentration of the precipitating reagent should be low with effective stirring to maintain low relative supersaturation for the growth of large crystals. In homogeneous precipitation, the precipitant is slowly generated by a chemical reaction in the solution to avoid local reagent excesses. For example, urea decomposes gradually to...
4.5K
Volatilization01:10

Volatilization

4.5K
Volatilization gravimetry is an analytical technique that measures the mass lost due to the volatilization of the substance. This technique is used to estimate the amount of volatile material in a sample. To perform this method, heat a known amount of the sample to a high temperature in a crucible or other suitable vessel. The volatile substance in the sample evaporates, and the vapor is completely expelled from the crucible either by heating the sample or bubbling a stream of inert gas through...
4.5K
Precipitation Titration Curve: Analysis01:21

Precipitation Titration Curve: Analysis

1.7K
The precipitation titration curve demonstrates the change in concentration of one reactant with the volume of titrant added. During the titration of chloride ions with silver nitrate, the precipitation titration curve is divided into three regions: before, at, and after the equivalence point. Before the equivalence point, low redissolution of the sparingly soluble silver chloride precipitate gives a low silver ion concentration. However, in the second region, representing the equivalence point,...
1.7K
Types of Coprecipitation01:10

Types of Coprecipitation

4.8K
Coprecipitation is the contamination of a precipitate by otherwise soluble species and occurs via different processes. In colloidal precipitates, coprecipitation occurs via surface adsorption. For instance, barium sulfate has a primary layer of adsorbed barium ions and a secondary layer of nitrate counterions. This results in contamination of the precipitate by barium nitrate.
Sometimes, ions in a crystal lattice can undergo isomorphous replacement by inclusions of similar charge and size. For...
4.8K

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Methods of Soil Resampling to Monitor Changes in the Chemical Concentrations of Forest Soils
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A quantitative method to decompose SWE differences between regional climate models and reanalysis datasets.

Yun Xu1, Andrew Jones2, Alan Rhoades2

  • 1Lawrence Berkeley National Laboratory, Earth and Environment Sciences Area, Berkeley, CA, 94720, USA. yunxu@lbl.gov.

Scientific Reports
|November 13, 2019
PubMed
Summary
This summary is machine-generated.

Regional climate models struggle to accurately simulate snow water equivalent (SWE). Improving model resolution and accounting for precipitation, temperature, and topography biases are key to enhancing SWE simulations.

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Area of Science:

  • Climate modeling
  • Hydrology
  • Environmental science

Background:

  • Accurate simulation of snow water equivalent (SWE) is crucial for water resource management but remains challenging for regional climate models.
  • Complex interactions between precipitation, rain-snow partitioning, and radiative fluxes influence SWE, making precise modeling difficult.

Purpose of the Study:

  • To develop a framework for quantitatively decomposing SWE differences between regional climate models and reanalysis datasets.
  • To identify specific factors contributing to SWE biases in climate models, guiding future improvements.

Main Methods:

  • Applied a novel decomposition framework to four North American Coordinated Regional Downscaling Experiment (NA-CORDEX) models in the Sierra Nevada.
  • Analyzed SWE differences attributed to precipitation distribution/magnitude, ablation, temperature, and topography biases across various spatial resolutions (0.44° to 0.11°).

Main Results:

  • Models generally underestimated SWE compared to the Landsat-Era Sierra Nevada Snow Reanalysis (SNSR) dataset.
  • Higher model resolution (0.11°) significantly improved SWE simulation by 35%, reducing dry and warm biases linked to unresolved topography.
  • Other contributing factors to SWE bias included precipitation distribution, cold biases from topographic correction, rain-snow partitioning uncertainties, and high ablation biases.

Conclusions:

  • Unresolved topography significantly impacts SWE simulation, with higher resolution models showing improvement.
  • Multiple factors, including precipitation patterns and ablation processes, contribute to SWE biases, necessitating a multi-faceted approach for model enhancement.
  • This study provides critical insights into climate model performance for SWE simulation and offers guidance for developing more accurate models.