Related Experiment Video

Updated: Jan 3, 2026

Line Shape Analysis of Dynamic NMR Spectra for Characterizing Coordination Sphere Rearrangements at a Chiral Rhenium Polyhydride Complex
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Line Shape Analysis of Dynamic NMR Spectra for Characterizing Coordination Sphere Rearrangements at a Chiral Rhenium Polyhydride Complex

Published on: July 27, 2022

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A Stable Cyclic (R2 SnAu)3 Anion Having In-Plane σ-Möbius Aromaticity

Liliang Wang1, Jian Xu1, Mitsuo Kira1

  • 1Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education, Hangzhou Normal University, No.2318, Yuhangtang Rd, Hangzhou, Zhejiang, 311121, P. R. China.

Angewandte Chemie (International Ed. in English)
|November 22, 2019
PubMed
Summary

A novel cyclic tin-gold anion, (R2SnAu)3(3-), was synthesized and characterized. This stable, blue, σ-aromatic anion exhibits an unprecedented Möbius orbital array, challenging previous understandings of anti-aromaticity.

Keywords:
gold complexeslow-valent compoundsstannylenesσ-Hückel aromaticityσ-Möbius aromaticity

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