3D Carbon Foam Supported Edge-Rich N-Doped MoS₂ Nanoflakes for Enhanced Electrocatalytic Hydrogen Evolution

Molybdenum disulfide (MoS₂ ) is one of the most promising alternatives to the Pt-based electrocatalysts for the hydrogen evolution reaction (HER). However, its performance is currently limited by insufficient active edge sites and poor electron transport. Hence, enormous efforts have been devoted to constructing more active edge sites and improving conductivity to obtain enhanced electrocatalytic performance. Herein, the 3D carbon foam (denoted as CF) supported edge-rich N-doped MoS₂ nanoflakes were successfully fabricated by using the commercially available polyurethane foam (PU) as the 3D substrate and PMo₁₂ O₄₀ ^3- clusters (denoted as PMo₁₂ ) as the Mo source through redox polymerization, followed by sulfurization. Owing to the uniform distribution of nanoscale Mo sources and 3D carbon foam substrate, the as-prepared MoS₂ -CF composite possessed well-exposed active edge sites and enhanced electrical conductivity. Systematic investigation demonstrated that the MoS₂ -CF composite showed high HER performance with a low overpotential of 92 mV in 1.0 m KOH and 155 mV in 0.5 m H₂ SO₄ at a current density of 10 mA cm^-2 . This work offers a new pathway for the rational design of MoS₂ -based HER electrocatalysts.