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Related Concept Videos

Molecular and Ionic Solids02:54

Molecular and Ionic Solids

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Crystalline solids are divided into four types: molecular, ionic, metallic, and covalent network based on the type of constituent units and their interparticle interactions.
Molecular Solids
Molecular crystalline solids, such as ice, sucrose (table sugar), and iodine, are solids that are composed of neutral molecules as their constituent units. These molecules are held together by weak intermolecular forces such as London dispersion forces, dipole-dipole interactions, or hydrogen bonds, which...
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Overview
When atoms gain or lose electrons to achieve a more stable electron configuration they form ions. Ionic bonds are electrostatic attractions between ions with opposite charges. Ionic compounds are rigid and brittle when solid and may dissociate into their constituent ions in water. Covalent compounds, by contrast, remain intact unless a chemical reaction breaks them.
Opposing Charges Hold Ions Together in Ionic Compounds
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Batteries and Fuel Cells03:12

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A battery is a galvanic cell that is used as a source of electrical power for specific applications. Modern batteries exist in a multitude of forms to accommodate various applications, from tiny button batteries such as those that power wristwatches to the very large batteries used to supply backup energy to municipal power grids. Some batteries are designed for single-use applications and cannot be recharged (primary cells), while others are based on conveniently reversible cell reactions that...
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Complexation Equilibria: Factors Influencing Stability of Complexes01:09

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In complexation reactions, metal cations are the electron pair acceptors, and the ligands are the electron pair donors. The stability of the metal complexes depends primarily on the complexing ability of the central metal ion and the nature of the ligands. Generally, the complexing ability of the metal ion depends on the size and charge of the ion. As the metal ion size increases, the stability of the metal complexes decreases, provided that the valency of the metal ion and the ligands remain...
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Ionic Strength: Effects on Chemical Equilibria01:19

Ionic Strength: Effects on Chemical Equilibria

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The addition of an inert ionic compound increases the solubility of a sparingly soluble salt. For example, adding potassium nitrate to a saturated solution of calcium sulfate significantly enhances the solubility of calcium sulfate. Le Châtelier's principle cannot predict this shift in the equilibrium. Instead, this could be explained in terms of changes in the effective concentration of the ions in solution in the presence of added inert salt.
In this solution, the primary...
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Interfacial Electrochemical Methods: Overview01:06

Interfacial Electrochemical Methods: Overview

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Interfacial electrochemical methods focus on the phenomena occurring at the boundary between an electrode and a solution, as opposed to bulk methods that concentrate on the solution's overall properties. These interfacial methods are classified as either static or dynamic based on the presence of a nonzero current in the electrochemical cell and the consistency of analyte concentrations. Static methods, such as potentiometry, measure the cell's potential without any significant current...
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Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications
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Approaching Practically Accessible Solid-State Batteries: Stability Issues Related to Solid Electrolytes and

Rusong Chen1,2, Qinghao Li1, Xiqian Yu1,2

  • 1Beijing Advanced Innovation Center for Materials Genome Engineering, Key Laboratory for Renewable Energy, Beijing Key Laboratory for New Energy Materials and Devices, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China.

Chemical Reviews
|November 26, 2019
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Summary
This summary is machine-generated.

Solid-state batteries offer higher energy density and safety than lithium-ion batteries. This review addresses challenges in solid-state electrolyte stability and interface design for practical energy storage applications.

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Area of Science:

  • Materials Science
  • Electrochemistry
  • Energy Storage

Background:

  • Solid-state batteries (SSBs) are advanced energy storage devices with potential for higher energy density and safety compared to conventional lithium-ion batteries.
  • Despite their promise, significant challenges hinder the development of cost-effective, scalable SSBs with long cycle life for applications like electric vehicles and grid storage.

Purpose of the Study:

  • This review provides an overview of scientific challenges, fundamental mechanisms, and design strategies for solid-state batteries.
  • It specifically focuses on the stability issues of solid-state electrolytes and their interfaces with electrode materials.
  • The aim is to summarize current knowledge and offer perspectives for future development.

Main Methods:

  • A comprehensive review of existing literature on solid-state battery technologies, focusing on electrolyte types and stability.
  • Discussion of chemical, electrochemical, mechanical, and thermal stability issues of solid-state electrolytes.
  • Summary of optimization strategies and advanced characterization techniques, including in situ and operando methods.

Main Results:

  • Solid-state electrolytes face critical stability challenges at the electrolyte-electrode interfaces, impacting overall battery performance.
  • Understanding these stability issues is crucial for designing robust solid-state batteries.
  • Various optimization strategies and advanced characterization techniques are being employed to address these challenges.

Conclusions:

  • Overcoming stability issues in solid-state electrolytes and their interfaces is paramount for realizing practical, high-performance solid-state batteries.
  • Further research into fundamental mechanisms and advanced characterization is needed.
  • Future design strategies should prioritize interfacial stability for scalable and reliable energy storage solutions.