Disposable pipette extraction using a selective sorbent for carbendazim residues in orange juice

In this work, a selective sorbent for carbendazim was prepared by the thermal immobilization of the poly(glycidoxypropylmethyl-co-dimethylsiloxane), PGDMS, on silica. The lab-made Si(PGDMS) sorbent was physicochemically and morphologically characterized and was used into the pipette tip for the disposable pipette extraction (DPX) of carbendazim residues of orange juice. The DPX method was optimized from a central composite design and validated according to the SANTE/11813/2017 document recommended by the European Union. The proposed method presented recoveries between 93 and 110% with RSD <16% and the limit of quantification below the MRL for carbendazim in citrus. The whole sample preparation process was carried out at less than 3 min, with good accuracy and precision without the need of any cleanup step or electrical equipment, allowing its portability for the extraction of carbendazim residues in orange juice.