Emerging Layered Metallic Vanadium Disulfide for Rechargeable Metal-Ion Batteries: Progress and Opportunities

Rechargeable metal-ion batteries (RMIBs), as one of the most viable technologies for electric vehicles (EVs) and large-scale energy storage (EES), have received extensive research attention for a long time. Electrode materials play a decisive role on capacity, energy, and power density, which directly affect the practical applications of RMIBs in EVs and EES. As an electrode material, layered metallic vanadium disulfide (VS₂ ) has theoretically and experimentally produced inspiring results because of its synthetic characteristics of continuously adjustable V valence, large interlayer spacing, weak interlayer interactions, and high surface activity. Herein, the synthetic strategies, theoretical metal-ion storage sites, diffusion kinetics, and experimental electrochemical reaction mechanisms of VS₂ for RMIBs are systematically introduced. Emphatically, the critical issues that affect the metal-ion storage properties of the VS₂ electrode and three major enhancement strategies, namely, optimizing the electrolyte and cutoff voltage, constructing a space-confined structure, and controlling the crystal structure are summarized, with the aim of promoting the development of transition-metal dichalcogenides. Finally, the challenges and opportunities for the future development of VS₂ in the energy-storage field are presented. It is hoped that this review can attract attention from researchers for investigations into emerging layered metallic VS₂ and provide insights toward the design of an excellent VS₂ electrode material for next-generation, high-performance RMIBs.