Comparison of different disinfection processes for controlling disinfection by-product formation in rainwater

With increasing shortage of clean water, rainwater has been considered as a precious alternative drinking water source. The processes applied to rainwater treatment are responsible for the safety of drinking water. Therefore, we systematically compared different disinfection processes to evaluate the control of disinfection by-product (DBP) formation and integrated cyto- and genotoxicity of the treated rainwater for the first time. The evaluated disinfection processes included chlorination and chloramination, pre-oxidation by potassium permanganate (KMnO₄) and potassium ferrate (K₂FeO₄), ultraviolet/hydrogen peroxide (UV/H₂O₂), and ultraviolet/persulfate (UV/PS) processes. The results revealed that chloramination was effective for controlling the formation of carbonaceous DBPs (C-DBPs), but not nitrogenous DBPs (N-DBPs). Compared to KMnO₄ pre-oxidation, better reduction of almost all DBPs was observed during K₂FeO₄ pre-oxidation. According to the calculation of cytotoxicity index (CTI) and genotoxicity index (GTI), cyto- and genotoxicity of the samples decreased obviously at the dosage of ≥ 2.0 mg/L KMnO₄ and K₂FeO₄. The control of the cyto- and genotoxicity of the formed DBPs from the two UV-related AOPs was more effective at the dosage of ≥ 1.0 mM PS and ≥ 5.0 mM H₂O₂. Moreover, UV/PS was much more powerful to alter the structure of DBP precursors in rainwater.