A High-Efficiency CuO/CeO₂ Catalyst for Diclofenac Degradation in Fenton-Like System

An efficient Fenton-like catalyst CuO/CeO₂ was synthesized using ultrasonic impregnation and used to remove diclofenac from water. The catalyst was characterized by N₂ adsorption-desorption, SEM-EDS, XRD, HRTEM, Raman, and XPS analyses. Results showed that CuO/CeO₂ possessed large surface area, high porosity, and fine elements dispersion. Cu was loaded in CeO₂, which increased the oxygen vacancies. The exposed crystal face of CeO₂ (200) was beneficial to the catalytic activity. The diclofenac removal experiment showed that there was a synergistic effect between CuO and CeO₂, which might be caused by more oxygen vacancies generation and electronic interactions between Cu and Ce species. The experimental conditions were optimized, including pH, catalyst and H₂O₂ dosages, and 86.62% diclofenac removal was achieved. Diclofenac oxidation by ·OH and adsorbed oxygen species was the main mechanism for its removal in this Fenton-like system.