Fluorescent carbon nanodots-based artificial tongue for determining and discriminating cigarettes

Smoking can cause cigarette-related diseases and pose serious threat to human health. Its dangers can be effectively controlled by discriminating cigarettes and monitoring cigarette quality. Herein, a kind of artificial tongue technique based on the indicator displacement assay (IDA) was developed and applied to determine and discriminate cigarettes and their main ingredients (saccharides, organic acids and nicotine). This method was constructed using carbon nanodots (CDs) as a fluorescent indicator and various concentrations of silver ion (Ag⁺) as a fluorescent regulator. A cigarette extracting solution was prepared to interact with an artificial tongue and produce fluorescence fingerprints. Twenty-nine kinds of cigarettes can be well discriminated in terms of category (flue-cured cigarette, blended cigarette and cigar), brand, origin (domestic or foreign cigarettes) after processing and visualizing the response fingerprints. The artificial tongue fluorescent sensor array can sensitively detect nine kinds of tobacco-based chemical ingredients and discriminate them between different concentrations. The as-prepared fluorescent artificial tongue is a promising platform for monitoring cigarette quality and controlling the harmful effects of smoking because of its cheap material requirements, simple operation, and good performance.