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Colloidal syntheses of zero-dimensional Cs4SnX6 (X = Br, I) nanocrystals with high emission efficiencies
1Department of Chemistry and Shenzhen Engineering Research Center for Frontier Materials Synthesis at High Pressures, Southern University of Science and Technology (SUSTech), Shenzhen, Guangdong 518055, P. R. China. quanzw@sustech.edu.cn.
Abstract:
Phase-pure all-inorganic zero-dimensional (0D) tin halide Cs4SnX6 (X = Br, I) nanocrystals (NCs) are successfully prepared for the first time. The as-prepared Cs4SnBr6 NCs exhibit a strongly Stokes-shifted broadband emission with a high photoluminescence quantum yield (PLQY) of 21% at room temperature.

