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The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes
Published on: April 10, 2015
Reactions of Uranium With the Platinide Elements. I. The Uranium-Ruthenium System
1Institute for Materials Research, National Bureau of Standards, Washington, D.C. 20234.
Abstract:
The phase diagram of the uranium-ruthenium system was constructed from data obtained by thermal analysis, metallographic examination, and x-ray diffraction. The system is characterized by five intermetallic compounds: U2Ru, formed peritectically near 937 °C; "URu," melting congruently near 1158 °C; U3Ru4, formed peritectically near 1163 °C; U3Ru5, formed peritectically near 1182 °C; and URu3, formed peritectically at about 1850 °C. "URu" has a solid-state transition at about 795 °C. One eutectic occurs near 886 °C and 18.5 atomic percent (a/o) ruthenium, and a second at about 1148 °C and 49 a/o ruthenium. The maximum solid solubilities are about 7.5 a/o ruthenium in uranium and near 1.3 a/o uranium in ruthenium. Ruthenium lowers the gamma-uranium transformation to near 691 °C and the beta-transformation to near 625 °C.
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