Jove
Visualize
Contact Us
JoVE
x logofacebook logolinkedin logoyoutube logo
ABOUT JoVE
OverviewLeadershipBlogJoVE Help Center
AUTHORS
Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
LIBRARIANS
TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
RESEARCH
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
EDUCATION
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
Terms & Conditions of Use
Privacy Policy
Policies

Related Concept Videos

Molecular and Ionic Solids02:54

Molecular and Ionic Solids

19.7K
Crystalline solids are divided into four types: molecular, ionic, metallic, and covalent network based on the type of constituent units and their interparticle interactions.
Molecular Solids
Molecular crystalline solids, such as ice, sucrose (table sugar), and iodine, are solids that are composed of neutral molecules as their constituent units. These molecules are held together by weak intermolecular forces such as London dispersion forces, dipole-dipole interactions, or hydrogen bonds, which...
19.7K
Ionic Crystal Structures02:42

Ionic Crystal Structures

16.6K
Ionic crystals consist of two or more different kinds of ions that usually have different sizes. The packing of these ions into a crystal structure is more complex than the packing of metal atoms that are the same size.
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
16.6K
Metallic Solids02:37

Metallic Solids

20.3K
Metallic solids such as crystals of copper, aluminum, and iron are formed by metal atoms. The structure of metallic crystals is often described as a uniform distribution of atomic nuclei within a “sea” of delocalized electrons. The atoms within such a metallic solid are held together by a unique force known as metallic bonding that gives rise to many useful and varied bulk properties.
All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and malleability....
20.3K
Ionic Bonding and Electron Transfer02:48

Ionic Bonding and Electron Transfer

48.4K
Ions are atoms or molecules bearing an electrical charge. A cation (a positive ion) forms when a neutral atom loses one or more electrons from its valence shell, and an anion (a negative ion) forms when a neutral atom gains one or more electrons in its valence shell. Compounds composed of ions are called ionic compounds (or salts), and their constituent ions are held together by ionic bonds: electrostatic forces of attraction between oppositely charged cations and anions. 
48.4K
Network Covalent Solids02:18

Network Covalent Solids

15.9K
Network covalent solids contain a three-dimensional network of covalently bonded atoms as found in the crystal structures of nonmetals like diamond, graphite, silicon, and some covalent compounds, such as silicon dioxide (sand) and silicon carbide (carborundum, the abrasive on sandpaper). Many minerals have networks of covalent bonds.
To break or to melt a covalent network solid, covalent bonds must be broken. Because covalent bonds are relatively strong, covalent network solids are typically...
15.9K
Intermolecular Forces03:13

Intermolecular Forces

68.4K
Atoms and molecules interact through bonds (or forces): intramolecular and intermolecular. The forces are electrostatic as they arise from interactions (attractive or repulsive) between charged species (permanent, partial, or temporary charges) and exist with varying strengths between ions, polar, nonpolar, and neutral molecules. The different types of intermolecular forces are ion–dipole, dipole–dipole, hydrogen bonds, and dispersion; among these, dipole–dipole, hydrogen...
68.4K

You might also read

Related Articles

Articles linked to this work by shared authors, journal, and citation graph.

Sort by
Same author

Aptamer-based fluorescence "off-on" sensor for EGFR-positive lung cancer CTCs using streptavidin magnetic beads and N-CQDs@Ag⁺.

Mikrochimica acta·2026
Same author

Erratum for Shou et al., "Increased intestinal permeability and bile acid accumulation via inhibition of the FXR-SHP pathway contribute to coumarin-induced systemic inflammation".

Microbiology spectrum·2026
Same author

Digital technologies in care for older adults living alone: a scoping review.

Innovation in aging·2026
Same author

Computer-aided diagnosis system for thoracic computed tomography of rib fractures in older emergency patients: A preliminary study.

PloS one·2026
Same author

Pulmonary ground-glass opacity associated with cystic airspace: clinicopathological features and aggressiveness.

Translational lung cancer research·2026
Same author

A Review of the Pharmacodynamics and Pharmacokinetics of Albiflorin.

Combinatorial chemistry & high throughput screening·2026

Related Experiment Video

Updated: Jan 2, 2026

Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications
05:33

Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications

Published on: August 12, 2013

22.1K

Li15P4S16Cl3, a Lithium Chlorothiophosphate as a Solid-State Ionic Conductor.

Zhantao Liu1, Tatiana Zinkevich2, Sylvio Indris2

  • 1The Woodruff School of Mechanical Engineering , Georgia Institute of Technology , Atlanta , Georgia 30332 , United States.

Inorganic Chemistry
|December 13, 2019
PubMed
Summary

A new solid lithium chlorothiophosphate electrolyte, Li15P4S16Cl3, was discovered for all-solid-state batteries. This material offers good stability and facile synthesis, presenting a novel crystal structure for solid-state electrolyte development.

More Related Videos

From Molecules to Materials: Engineering New Ionic Liquid Crystals Through Halogen Bonding
06:44

From Molecules to Materials: Engineering New Ionic Liquid Crystals Through Halogen Bonding

Published on: March 24, 2018

69.5K
Synthesis of Ionic Liquid Based Electrolytes, Assembly of Li-ion Batteries, and Measurements of Performance at High Temperature
11:04

Synthesis of Ionic Liquid Based Electrolytes, Assembly of Li-ion Batteries, and Measurements of Performance at High Temperature

Published on: December 20, 2016

13.3K

Related Experiment Videos

Last Updated: Jan 2, 2026

Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications
05:33

Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications

Published on: August 12, 2013

22.1K
From Molecules to Materials: Engineering New Ionic Liquid Crystals Through Halogen Bonding
06:44

From Molecules to Materials: Engineering New Ionic Liquid Crystals Through Halogen Bonding

Published on: March 24, 2018

69.5K
Synthesis of Ionic Liquid Based Electrolytes, Assembly of Li-ion Batteries, and Measurements of Performance at High Temperature
11:04

Synthesis of Ionic Liquid Based Electrolytes, Assembly of Li-ion Batteries, and Measurements of Performance at High Temperature

Published on: December 20, 2016

13.3K

Area of Science:

  • Materials Science
  • Electrochemistry
  • Solid-State Chemistry

Background:

  • All-solid-state batteries offer enhanced safety over conventional lithium-ion batteries due to the use of solid electrolytes.
  • Developing novel solid lithium-ion electrolytes is crucial for advancing battery technology.

Purpose of the Study:

  • To discover and characterize a new lithium chlorothiophosphate compound for solid-state electrolyte applications.
  • To investigate the crystal structure, synthesis, and Li+ transport properties of the novel compound.

Main Methods:

  • Solid-state reaction synthesis.
  • Neutron and synchrotron powder X-ray diffraction for crystal structure refinement.
  • Multiple solid-state Nuclear Magnetic Resonance (NMR) techniques (variable-temperature NMR line-shape analysis, NMR relaxometry, pulsed-field-gradient NMR) for Li+ transport investigation.

Main Results:

  • A novel lithium chlorothiophosphate, Li15P4S16Cl3, was successfully synthesized as a pure phase.
  • The crystal structure was determined to be space group I4̅3d.
  • Li15P4S16Cl3 exhibits good thermodynamic stability and was synthesized at a relatively low temperature (360 °C).
  • While exhibiting low room-temperature ionic conductivity, Li+ transport mechanisms were elucidated.

Conclusions:

  • Li15P4S16Cl3 represents a new crystal structure motif for the design of solid-state electrolytes.
  • Further research can build upon this structure to develop improved solid electrolytes for all-solid-state batteries.