Metallacycle Transfer and its Link to Light-Emitting Materials and Conjugated Polymers

Major advances in optoelectronic technologies (e. g., solar cells, organic light-emitting diodes, etc…) are prefaced by the discovery of new synthetic methodologies. In this review, the key role of the Fagan-Nugent reaction in enabling our team (and others) to gain access to new building blocks for luminescent materials and conjugated polymers bearing p-block elements will be described. The Fagan-Nugent reaction is extremely powerful as a synthetic tool since the efficient zirconium-element atom exchange involved affords a wide range of unsaturated inorganic heterocycles of controllable composition and function.