The improvement of photocatalysis O₂ production over BiVO₄ with amorphous FeOOH shell modification

A novel amorphous FeOOH modified BiVO₄ photocatalyst (A-FeOOH/BiVO₄) was successfully produced and characterized by various techniques. The results showed that amorphous FeOOH with about 2 nm thickness evenly covered on BiVO₄ surface, which caused resultant A-FeOOH/BiVO₄ exhibiting higher visible light photocatalytic performance for producing O₂ from water than BiVO₄. When the covered amount of amorphous FeOOH was 8%, the resultant photocatalyst possessed the best photocatalytic performance. To find the reasons for the improvement of photocatalytic property, electrochemical experiments, DRS, PL and BET, were also measured, the experimental results indicated that interface effect between amorphous FeOOH and BiVO₄ could conduce to migration of photogenerated charge, and exhibit stronger light responded capacity. These positive factors promoted A-FeOOH/BiVO₄ presenting improved the photocatalytic performance. In a word, the combination of amorphous FeOOH with BiVO₄ is an effective strategy to conquer important challenges in photocatalysis field.