Scandium(III) Triflate Catalyzed Direct Synthesis of N-Unprotected Ketimines
Yuta Kondo1, Tetsuya Kadota1, Yoshinobu Hirazawa1
1Graduate School of Pharmaceutical Sciences , Kyushu University , Maidashi 3-1-1 Higashi-ku , Fukuoka , Japan , 812-8582.
Abstract:
N-Unprotected ketimines are useful substrates and intermediates for synthesizing valuable nitrogen-containing compounds, but their potential applicability is limited by the available synthetic methods. To address this issue, we report a scandium(III) triflate catalyzed direct synthesis of N-unprotected ketimines. Using commercially available reagents and Lewis acid catalysts, ketones were directly transformed into the corresponding N-unprotected ketimines in high yields with broad functional group tolerance, even in multigram scales. The reactions were readily applicable for one-pot synthesis of important compounds such as a glycine Schiff base without isolation of N-unprotected ketimine intermediates. Preliminary mechanistic studies to clarify the reaction mechanism are also described.
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