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Updated: Dec 31, 2025

High-Contrast and Fast Photorheological Switching of a Twist-Bend Nematic Liquid Crystal
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A Rotorlike Supramolecular Assembly, {[K(18-crown-6)]PbI3}∞, with a Reversible Breaking-Symmetry Phase Transition

Guo-Jun Yuan1,2, Dong-Sheng Shao2, Bing-Wen Hu3

  • 1Key Laboratory of Advanced Functional Materials of Nanjing, Department of Chemistry , Nanjing Xiaozhuang University , Nanjing 211171 , P. R. China.

Inorganic Chemistry
|January 8, 2020
PubMed
Summary

A novel rotorlike crystal structure, {[K(18-crown-6)]PbI3}∞, exhibits a reversible phase transition around 305 K. This transition involves dynamic [K(18-crown-6)]+ cations acting as rotators within the crystal lattice.

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