Interface Formation between CdS and Alkali Postdeposition-Treated Cu(In,Ga)Se₂ Thin-Film Solar Cell Absorbers-Key To...

A combination of X-ray photoelectron/Auger electron spectroscopy and soft X-ray emission spectroscopy has been employed to investigate the impact of different alkali postdeposition treatments (PDTs) on the chemical structure of the (buried) CdS/Cu(In,Ga)Se₂ heterojunction: the key interface in chalcopyrite-based thin-film solar cells. Chemical bath deposited (CBD) CdS layers of different thicknesses on NaF PDT (CIGSe^NaF) and NaF + KF PDT (CIGSe^NaF+KF) Cu(In,Ga)Se₂ absorbers prepared at low temperature (to facilitate the use of flexible, e.g., polyimide, substrates) were studied. While we find the CdS/CIGSe^NaF interface to be mainly free of significant chemical interaction, in the proximity of the CdS/CIGSe^NaF+KF interface, an elemental redistribution involving Cd, In, K, S, and Se is revealed. For the early stages of the CBD-CdS process, our findings are in agreement with the conversion of the K-In-Se-type layer present on the CIGSe^NaF+KF surface into a mixed Cd-In-(O,OH,S,Se)-type layer, probably having some Cd-In and (S,O)-Se composition gradients. For long CBD times-independent of employed PDT-we find the buffer material to be best described by a Cd(O,OH,S)-like species rather than by a pure CdS buffer. These findings shed light on the observed performance leap of corresponding CdS/CIGSe^NaF+KF-based solar cells.