Crayfish shell biochar modified with magnesium chloride and its effect on lead removal in aqueous solution

In this study, crayfish shell was pyrolyzed at 600 °C to obtain an unmodified biochar (CS600). MgCl₂ was used as a modifier to pretreat crayfish shell to produce a modified biochar (CS600-MgCl₂) under the same pyrolysis conditions. The two biochars were characterized for physicochemical properties and evaluated for lead (Pb²⁺) sorption ability to determine the modification mechanism. Mono-element batch adsorption experiments were conducted to compare the sorption performances of CS600 and CS600-MgCl₂ to Pb²⁺ in aqueous solutions. All the experiments were carried out at pH of 7. According to the Freundlich-Langmuir model, CS600-MgCl₂ had a higher adsorption capacity (152.3 mg/g) than CS600 (134.3 mg/g). FTIR, SEM, XRD, BET, and ICP analyses were applied to inform the interpretation of the mechanism. CS600 was calcium-rich and mainly removed Pb²⁺ through the ion exchange mechanism by replacing Ca²⁺ in the biochar. The increased Pb²⁺ adsorption capacity of CS600-MgCl₂ was mainly due to the enlarged specific surface area and the formation of Mg₃(OH)₅Cl·4H₂O on the modified biochar. Findings of this study suggest that both CS600 and CS600-MgCl₂ can be used to remove heavy metal ions from wastewater and MgCl₂ can improve the sorption performance of biochar.