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Updated: Dec 31, 2025

Measurement and Analysis of Atomic Hydrogen and Diatomic Molecular AlO, C2, CN, and TiO Spectra Following Laser-induced Optical Breakdown
Published on: February 14, 2014
Classical Path Methods in Line Broadening. II. Application to the Lyman Series of Hydrogen
Earl W Smith1, C R Vidal1, J Cooper1
1Institute for Basic Standards, National Bureau of Standards, Boulder, Colorado 80302.
Abstract:
The use of the classical path approximation in line broadening theory is illustrated in a development of the familiar impact and one-electron theories. The one-electron theory which is presented is an improved version of the usual one-electron theory; this improved version of the theory provides a consistent description of a line profile from the halfwidth to the quasi-static wings. The validity criteria for the impact and one-electron theories are discussed in detail and a comparison of the theories is made with a view toward the development of a more general theory containing elements of both. To avoid unnecessary mathematical complications and to provide a more transparent comparison of the theories, the Stark broadening of the Lyman series in hydrogen is used as a specific example.
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