Removal of phosphate from wastewater by modified bentonite entrapped in Ca-alginate beads

Methods of removing phosphate from wastewater with a low phosphate concentration are of great environmental significance. In this study, immobilized beads were prepared by entrapping modified bentonite powder in calcium-alginate (Al-NaBT-CA), and the potential of the beads for phosphate removal from wastewater was investigated. The effects of pH (1-10) and initial phosphate concentration (0.5-50 mg/L) were also examined in batch experiments with Al-NaBT-CA beads. The optimum pH value for phosphate removal by Al-NaBT-CA beads was pH 3. In addition, a high initial phosphate concentration promoted phosphate adsorption. Adsorption kinetics showed that the adsorption of phosphate using beads followed a pseudo-second-order kinetic model (R² = 0.98-0.99). The adsorption isotherm data was well fitted by the Sips adsorption model. The maximum phosphate adsorption capacity of the Al-NaBT-CA beads was 15.77 mg/g, which was slightly less than that of the modified powder. The specific surface area of the Al-NaBT-CA beads was 17.01 m²/g, and their average pore size was 13.41 nm. Scanning electron microscopy suggested that the high inner porosity and rough outer surface of the beads facilitated phosphate transfer.