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A universal strategy for fabrication and morphology control of polyoxometalate-based metal-organic frameworks
Xiao-Hui Li1, Yi-Wei Liu1, Ying Lu1
1Key Laboratory of Polyoxometalate Science of the Ministry of Education, College of Chemistry, Northeast Normal University, Changchun, Jilin 130024, P. R. China. liusx@nenu.edu.cn luy968@nenu.edu.cn.
Chemical Communications (Cambridge, England)
|January 17, 2020
Abstract:
A novel method is proposed to fabricate polyoxometalate-based metal-organic frameworks (POM@MOFs) by using the ability of POMs to oxidize metals to cations. The morphology-controlled growth of POM@MOFs (NENU-n) is achieved in the absence of any modulators and an effect of polyoxoanion charge number on morphology is observed.
