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![The Synthesis of [Sn10SiSiMe334]2- Using a Metastable SnI Halide Solution Synthesized via a Co-condensation Technique](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F54498.jpg&w=3840&q=50)
The Synthesis of [Sn10SiSiMe334]2- Using a Metastable SnI Halide Solution Synthesized via a Co-condensation Technique
Published on: November 28, 2016
An Air-Stable Heterobimetallic Si2 M2 Tetrahedral Cluster
Gizem Dübek1, Franziska Hanusch1, Dominik Munz2
1Department of Chemistry, Catalysis Research Center and Institute of Silicon Chemistry, Technical University Munich, Lichtenbergstraße 4, 85748, Garching bei München, Germany.
Abstract:
Air- and moisture-stable heterobimetallic tetrahedral clusters [Cp(CO)2 MSiR]2 (M=Mo or W; R=SitBu3 ) were isolated from the reaction of N-heterocyclic carbene (NHC) stabilized silyl(silylidene) metal complexes Cp(CO)2 M=Si(SitBu3 )NHC with a mild Lewis acid (BPh3 ). Alternatively, treatment of the NHC-stabilized silylidene complex Cp(CO)2 W=Si(SitBu3 )NHC with stronger Lewis acids such as AlCl3 or B(C6 F5 )3 resulted in the reversible coordination of the Lewis acid to one of the carbonyl ligands. Computational investigations revealed that the dimerization of the intermediate metal silylidyne (M≡Si) complex to a tetrahedral cluster instead of a planar four-membered ring is due to steric bulk.
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