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Related Concept Videos

Raman Spectroscopy Instrumentation: Overview01:26

Raman Spectroscopy Instrumentation: Overview

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A conventional Raman spectrophotometer includes a laser source, a sample holding system, a wavelength selector, and a detector.
The monochromatic laser source, typically using visible or near-infrared radiation, generates a highly focused beam of light. This light interacts with the molecules of the sample, scattering some of the light. Liquid and gaseous samples are usually tested in ordinary glass capillaries, while solids can be analyzed as powders packed in capillaries or as potassium...
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Raman Spectroscopy: Overview01:20

Raman Spectroscopy: Overview

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The underlying principle of Raman spectroscopy is based on the interaction between light and matter, specifically molecules' inelastic scattering of photons. When a monochromatic beam of light, typically from a laser source, interacts with a sample, most scattered light has the same frequency as the incident light. This is known as Rayleigh scattering.
However, a small fraction of the scattered light exhibits a frequency shift due to the exchange of energy between the incident photons and...
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2D NMR: Homonuclear Correlation Spectroscopy (COSY)01:06

2D NMR: Homonuclear Correlation Spectroscopy (COSY)

1.8K
Homonuclear correlation spectroscopy, or COSY, is a 2-dimensional NMR technique that provides information about coupled protons. Typically, the geminal and vicinal coupling are observed. For example, consider the COSY spectrum of ethyl acetate, where its 1D proton NMR spectrum is plotted along the vertical and horizontal axes with their corresponding chemical shift scale. Three spots on the diagonal corresponding to the three peaks in the 1D proton spectrum are called diagonal peaks. The COSY...
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Spectroscopy of Carboxylic Acid Derivatives01:26

Spectroscopy of Carboxylic Acid Derivatives

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Infrared spectroscopy is primarily used to determine the types of bonds and functional groups. In carboxylic acid derivatives, a typical carbonyl bond absorption is observed around 1650–1850 cm−1. For esters, the absorption is recorded at around 1740 cm−1, while acid halides show the absorption at about 1800 cm−1. Another acid derivative, the acid anhydrides, exhibit two carbonyl absorption around 1760 cm−1 and 1820 cm−1, arising from the symmetrical and...
2.9K
2D NMR: Overview of Homonuclear Correlation Techniques01:16

2D NMR: Overview of Homonuclear Correlation Techniques

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Homonuclear correlation spectroscopy (COSY) is a powerful technique used in Nuclear Magnetic Resonance (NMR) spectroscopy to study the correlations between nuclei of the same type within a molecule. It provides information about scalar couplings between adjacent nuclei, which helps determine connectivity and structural information. There are several COSY variants, each with its unique strengths and experimental parameters.
COSY90 is the standard two-dimensional (2D) COSY experiment that...
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¹³C NMR: ¹H–¹³C Decoupling01:04

¹³C NMR: ¹H–¹³C Decoupling

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The probability of having two carbon-13 atoms next to each other is negligible because of the low natural abundance of carbon-13. Consequently, peak splitting due to carbon-carbon spin-spin coupling is not observed in spectra. However, protons up to three sigma bonds away split the carbon signal according to the n+1 rule, resulting in complicated spectra.
A broadband decoupling technique is used to simplify these complex, sometimes overlapping, signals. Broadband decoupling relies on a...
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Compressive Sensing Spectroscopy Using a Residual Convolutional Neural Network.

Cheolsun Kim1, Dongju Park1, Heung-No Lee1

  • 1School of Electrical Engineering and Computer Science, Gwangju Institute of Science and Technology, Gwangju 61005, Korea.

Sensors (Basel, Switzerland)
|January 25, 2020
PubMed
Summary
This summary is machine-generated.

A new Residual Convolutional Neural Network (ResCNN) improves spectral recovery from compressed measurements. This novel method offers superior performance and faster convergence compared to existing techniques for compact spectrometer development.

Keywords:
compressed sensingdeep learningdictionary learninginverse problemssparse recoveryspectroscopy

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Area of Science:

  • Spectroscopy
  • Signal Processing
  • Machine Learning

Background:

  • Compressive sensing (CS) spectroscopy enables compact spectrometer development.
  • Spectrum reconstruction is a key challenge in CS spectroscopy.
  • Existing methods like sparse recovery and standard CNNs have limitations.

Purpose of the Study:

  • To propose a novel Residual Convolutional Neural Network (ResCNN) for spectrum reconstruction from compressed measurements.
  • To evaluate the performance of ResCNN against existing spectral recovery techniques.
  • To demonstrate the advantages of ResCNN in terms of accuracy, stability, and speed.

Main Methods:

  • Developed a ResCNN architecture with learnable layers and residual connections.
  • Trained the ResCNN using both synthetic and measured spectral datasets.
  • Compared ResCNN performance against sparse recovery methods and standard Convolutional Neural Networks (CNNs) using RMSE and PSNR metrics.

Main Results:

  • ResCNN demonstrated superior spectral recovery performance compared to existing methods.
  • Achieved better average root mean squared errors (RMSEs) and peak signal to noise ratios (PSNRs).
  • ResCNN showed stable reconstructions even under noisy conditions and faster convergence than standard CNNs.

Conclusions:

  • ResCNN offers a powerful and efficient approach for spectral reconstruction in compressive sensing spectroscopy.
  • The method eliminates the need for prior knowledge of sparsifying bases or spectral features.
  • ResCNN advances the development of compact and high-performance spectrometers.