Pd-based nanoparticles: Plant-assisted biosynthesis, characterization, mechanism, stability, catalytic and...

Among various metal nanoparticles, palladium nanoparticles (Pd NPs) are one of the most important and fascinating nanomaterials. An important concern about the preparation of Pd NPs is the formation of toxic by-products, dangerous wastes and harmful pollutants. The best solution to exclude and/or minimize these toxic substances is plant mediated biosynthesis of Pd NPs. Biogenic Pd-based NPs from plant extracts have been identified as valuable nanocatalysts in various catalytic reactions because of their excellent activities and selectivity. They have captured the attention of researchers owing to their economical, sustainable, green and eco-friendly nature. This review attempts to cover the recent progresses in the fabrication, characterization and broad applications of biogenic Pd NPs in environmental and catalytic systems. In addition, the stability of biosynthesized Pd NPs and mechanism of their formation are investigated.