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Updated: Dec 30, 2025
High Resolution Physical Characterization of Single Metallic Nanoparticles
Published on: June 28, 2019
0D to 1D Switching of Hybrid Polyoxometalate Assemblies at the Nanoscale by Using Molecular Control
1State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029 (P.R. China), Fax: (+86) 10-64431832.
Abstract:
Watered down: Polyoxometalate (POM) hybrids based on [C16 H36 N]4 [SiW11 O40 (SiCH2 CH2 CH2 NH2 ⋅HCl)2 ] covalently functionalized with different lengths of alkyl chains (n=0, 5, or 10) terminated with azobenzene moieties have been successfully prepared. The assembly behavior of these POMs can be affected by hydrophobic and π-π interactions by finely tuning the lengths of the alkyl chains in different ratios of CH3 CN/H2 O.
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