Stimuli-Responsive Naphthalene Diimide as Invisible Ink: A Rewritable Fluorescent Platform for Anti-Counterfeiting

Herein, we report an approach to combat counterfeiting and storage of valuable information based on the solid-state fluorescence switching behavior of isoniazid functionalized naphthalene diimide (ISO_NDI) in response to an external stimuli (i. e., HCl vapor). The unique feature of ISO_NDI is further utilized to develop an invisible ink (ISO_NDI-PVA) with commercial polymer polyvinyl alcohol (PVA). A solid-state fluorescence recovery was observed while loading with HCl vapors. This exclusive property of the material could be applied directly as a security ink for confidential data storage purpose. Based on above strategy, we successfully realized the rewritable application by using ISO_NDI-PVA ink and confirm its practical efficacy on various substrates by creating different patterns. The solid-state fluorescence switching behavior of ISO_NDI-PVA ink exhibited reversible on/off signal for multiple cycles under the influence of HCl/NH₃ vapors. Mechanistic investigation supports a clear participation of intermolecular charge transfer (ICT) phenomenon in the solid-state fluorescence switching property. The ease of fabricating the ink with invisible to visible characteristics in response to HCl vapors provides new opportunities for exploring the application of ISO_NDI-PVA as invisible ink for targeted security applications.