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Updated: Dec 29, 2025

Molecular Entanglement and Electrospinnability of Biopolymers
Published on: September 3, 2014
Electric Field Enhances Shear Resistance of Polymer Melts via Orientational Polarization in Microstructures
Miao Huo1, Yunlong Guo1,2
1University of Michigan-Shanghai Jiao Tong University Joint Institute, Shanghai Jiao Tong University, Shanghai 200240, China.
Abstract:
In this paper, we studied the alteration of viscoelastic properties of a neat poly(methyl methacrylate) (PMMA), induced by an applied external electric field. The rheological properties of PMMA are measured using a rotational rheometer at elevated temperatures. The electric field effect on the shear resistance of the polymer was studied by examining rheological responses under difference experimental scenarios. We find that the external electric field can remarkably enhance shear resistance and prevent flow of PMMA melt, enabling it to behave more predictably at high temperatures. Dynamic rheological analysis illustrates that the external electric field speeds up the recovery of mechanical properties of the PMMA melt after large deformations, whereas the PMMA melt exhibits thixotropic behaviors. The recovery velocity is influenced by the strength of the electric field, specifically, and is found to be proportional to the electric field strength. Our experimental characterization may provide new evidence on the tuning mechanical properties of polymer melts via controlling segmental polarization.
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