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Energy, Particle, and Photon Fluxes in Molecular Junctions
Hari Kumar Yadalam1, Shaul Mukamel2, Upendra Harbola1
1Department of Inorganic and Physical Chemistry, Indian Institute of Science, Bangalore 560012, India.
Abstract:
Electroluminescence from a current-carrying molecular junction at steady state is simulated. (Charge) particle conservation and energy conservation are satisfied by a perturbative expansion in the radiation/matter coupling. Our approach makes it possible to adopt standard tools of traditional (equilibrium) spectroscopy to study signals from open systems such as molecular junctions. The nonperturbative analysis of spontaneous light emission signals coincides with the perturbative approach for weak molecule-field coupling.
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