Assessment of persistent organic pollutants in surface sediments along Lebanese coastal zone

The levels of some persistent organic pollutants (POPs) along the Lebanese coastal zone (LCZ) were assessed by collecting15 surface sediments from five hotspot stations. Such stations were influenced by various industrial units, riverine input, and touristic activities. The levels of polycyclic aromatic hydrocarbons (∑16PAHs), their methylated derivatives (∑18Me-PAHs), and polychlorinated biphenyls (∑28PCBs) were in the range of 537-3773 μg∙kg^-1 dw, 187-1541 μg∙kg^-1 dw, and 143-303 μg∙kg^-1 dw respectively. Significant contamination was found at Beirut Port that is surrounded by a densely populated area and is subjected to multidisciplinary activities. Source identification of PAHs was confirmed by using the diagnostic ratio of PAHs with low molecular weight and high molecular weight (LMW/HMW). For PCBs, LCZ is polluted by higher chlorinated congeners with 4 to 9 chlorinated atoms generated from volatilization and combustion processes. Toxicity and biological risks were assessed using toxic equivalent quantity (TEQcarc) and sediment quality guideline quotient (SQGq).