Metal Oxide Oxidation Catalysts as Scaffolds for Perovskite Solar Cells

Whilst the highest power conversion efficiency (PCE) perovskite solar cell (PSC) devices that have reported to date have been fabricated by high temperature sintering (>500 °C) of mesoporous metal oxide scaffolds, lower temperature processing is desirable for increasing the range of substrates available and also decrease the energy requirements during device manufacture. In this work, titanium dioxide (TiO₂) mesoporous scaffolds have been compared with metal oxide oxidation catalysts: cerium dioxide (CeO₂) and manganese dioxide (MnO₂). For MnO₂, to the best of our knowledge, this is the first time a low energy band gap metal oxide has been used as a scaffold in the PSC devices. Thermal gravimetric analysis (TGA) shows that organic binder removal is completed at temperatures of 350 °C and 275 °C for CeO₂ and MnO₂, respectively. By comparison, the binder removal from TiO₂ pastes requires temperatures >500 °C. CH₃NH₃PbBr₃ PSC devices that were fabricated while using MnO₂ pastes sintered at 550 °C show slightly improved PCE (η = 3.9%) versus mesoporous TiO₂ devices (η = 3.8%) as a result of increased open circuit voltage (V_oc). However, the resultant PSC devices showed no efficiency despite apparently complete binder removal during lower temperature (325 °C) sintering using CeO₂ or MnO₂ pastes.