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Updated: Dec 27, 2025

Methods of Ex Situ and In Situ Investigations of Structural Transformations: The Case of Crystallization of Metallic Glasses
Published on: June 7, 2018
An investigation of pre-crystalline order, ruling out Pauli crystals and introducing Pauli anti-crystals
Mikael Fremling1,2, J K Slingerland3,4
1Institute for Theoretical Physics, Center for Extreme Matter and Emergent Phenomena, Utrecht University, Princetonplein 5, 3584 CC, Utrecht, The Netherlands. micke.fremling@gmail.com.
Abstract:
Fluid states of matter can locally exhibit characteristics of the onset of crystalline order. Traditionally this has been theoretically investigated using multipoint correlation functions. However new measurement techniques now allow multiparticle configurations of cold atomic systems to be observed directly. This has led to a search for new techniques to characterize the configurations that are likely to be observed. One of these techniques is the configuration density (CD), which has been used to argue for the formation of "Pauli crystals" by non-interacting electrons in e.g. a harmonic trap. We show here that such Pauli crystals do not exist, but that other other interesting spatial structures can occur in the form of an "anti-Crystal", where the fermions preferentially avoid a lattice of positions surrounding any given fermion. Further, we show that configuration densities must be treated with great care as naive application can lead to the identification of crystalline structures which are artifacts of the method and of no physical significance. We analyze the failure of the CD and suggest methods that might be more suitable for characterizing multiparticle correlations which may signal the onset of crystalline order. In particular, we introduce neighbour counting statistics (NCS), which is the full counting statistics of the particle number in a neighborhood of a given particle. We test this on two dimensional systems with emerging triangular and square crystal structures.
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