Manganese and Graphene Included Titanium Dioxide Composite Nanowires: Fabrication, Characterization and Enhanced...

We report the detailed microstructural, morphological, optical and photocatalytic studies of graphene (G) and manganese (Mn) co-doped titanium dioxide nanowires (TiO₂(G-Mn) NWs) prepared through facile combined electrospinning-hydrothermal processes. The as-prepared samples were thoroughly characterized using X-ray diffraction (XRD), transmission electron microscopy, X-ray photoelectron spectroscopy (XPS), Raman spectroscopy, and diffuse reflectance spectroscopy (DRS). XRD studies reveal the formation of mixed anatase-rutile phases or rutile phase depending on the dopant (Mn) precursor concentrations in the electrospinning dope and calcination temperature. The evaluation of lattice parameters revealed that the incorporation of Mn species and carbon atoms in to the lattice of anatase or rutile TiO₂ could occur through substituting the sites of oxygen atoms. XPS results confirm the existence of Mn²⁺/Mn³⁺ within the TiO₂ NW. Raman spectroscopy provides the evidence for structural modification because of the graphene inclusion in TiO₂ NW. The optical band gap of G-Mn including TiO₂ is much lower than pristine TiO₂ as confirmed through UV-vis DRS. The photocatalytic activities were evaluated by nitric oxide (NOx) degradation tests under visible light irradiation. Superior catalytic activity was witnessed for rutile G-Mn-co-doped TiO₂ NW over their anatase counterparts. The enhanced photocatalytic property was discussed based on the synergistic effects of doped G and Mn atoms and explained by plausible mechanisms.