Effective removal of methylene blue dye from water with nanocomposite ceramsites in a fixed-bed column

The study aims to remove methylene blue dye from water with a fixed-bed column packed with Cu₂O nanocomposite ceramsites. The column showed the advantages of fixed-bed column adsorption and photocatalytic oxidation. The Cu₂O nanocomposite ceramsites with strong photocatalytic oxidation activity and well-developed porous structure were successfully prepared with the chemical vapour deposition process, which also met with the China's industrial standard of CJ/T 299-2008 and China's national standard of GB 5085.3-2007. In the column experiments under the experimental conditions (initial pH was 3, reaction temperature was 25°C and flow rate was 33 mL/min), the breakthrough curve was much more smooth. The breakthrough time and saturation time under ultraviolet radiation were 36.0% and 26.83% longer than those under the conditions without ultraviolet radiation, because the micro-pore structure of ceramsite was closely related to optical excitation properties of nano-Cu₂O. The Yoon-Nelson and Adams-Bohart models were applied to describe the obtained breakthrough curves using non-linear regression, in which the Yoon-Nelson model gave the better prediction results for breakthrough curves, with R²>0.98. Besides, amines were the dominant intermediates at saturation point and final products were inorganic anions. This study confirmed that the fixed-bed column packed with Cu₂O nanocomposite ceramsites could efficiently treat methylene blue dye wastewater, due to the structure-function relationship between ceramsite and nano-Cu₂O.