Highly efficient and recyclable catalyst: porous Fe₃O₄-Au magnetic nanocomposites with tailored synthesis

In this work, we reported the tailored design of highly efficient Fe₃O₄-Au magnetic nanocomposite (MNP) catalysts. Fe₃O₄ nanocrystals with three different morphologies have been developed with engineered amounts of urea, and the plausible mechanism has been proposed. Then by controlling the amount of Au seeds, Fe₃O₄-Au MNPs with different morphologies and tunable Au deposition have been realized. Characterizations including x-ray diffraction (XRD), transmission electron microscopy (TEM), Mössbauer spectra, and elemental mapping are implemented to unveil the structural and physical characteristics of the successfully developed Fe₃O₄-Au MNPs with different morphologies. The catalytic ability of Fe₃O₄-Au MNPs with different morphologies have been compared by applying them to degrading RhB and 4-NP, meanwhile the correlation between the amount of Au seeds and the turnover frequency as well as the catalytic ability of Fe₃O₄-Au MNPs is investigated systematically. We found that the flower-like Fe₃O₄-Au MNPs with 20 ml Au seeds added achieved the best degradation efficiency of 96.7%, and their catalytic ability were almost unchanged after recycling. Out study sheds the light into the tailored design of highly efficient and recyclable catalysts for RhB and 4-NP.