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Updated: Dec 25, 2025

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Ethylene Polymerizations Using Parallel Pressure Reactors and a Kinetic Analysis of Chain Transfer Polymerization
Published on: November 27, 2015
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PVT and Vapor Pressure Measurements on Ethane
1Institute for Basic Standards, National Bureau of Standards, Boulder, Colorado 80302.
Summary
New measurements provide precise vapor pressure and PVT data for ethane across a wide temperature and density range. These findings enhance understanding of ethane
Area of Science:
- Thermodynamics
- Fluid Properties
- Chemical Engineering
Background:
- Accurate thermodynamic data is crucial for designing and optimizing chemical processes.
- Ethane is a key component in natural gas and petrochemical feedstocks.
- Existing data for ethane properties may have limitations in certain conditions.
Purpose of the Study:
- To report new, precise measurements of ethane vapor pressures.
- To present comprehensive pressure-volume-temperature (PVT) data for ethane.
- To cover a wide range of temperatures, pressures, and densities, including near-critical conditions.
Main Methods:
- Experimental determination of vapor pressures.
- Experimental determination of PVT properties using specialized apparatus.
- Measurements conducted from near the triple point up to 320 K and 33 MPa.
Main Results:
- New vapor pressure data for ethane from 160 K to the critical point.
- Extensive PVT data obtained, covering densities exceeding three times the critical density.
- High-accuracy data generated across a broad operational envelope.
Conclusions:
- The reported data significantly expands the available knowledge base for ethane.
- This study provides critical data for thermodynamic modeling and process simulation.
- The measurements validate and extend existing ethane property correlations.
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