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Mass transfer between microbubbles.

Yuqi Yang1, Matthew D Biviano2, Jixiang Guo3

  • 1State Key Laboratory of Heavy Oil Processing at Karamay, China University of Petroleum-Beijing at Karamay, Karamay 834000, China; Institute of Unconventional Oil and Gas Science and Technology, China University of Petroleum, Beijing 102249, China.

Journal of Colloid and Interface Science
|March 24, 2020
PubMed
Summary
This summary is machine-generated.

Interfacial coatings impact gas transport in foams. Anionic surfactants enhance mass transfer above critical micelle concentration, while polymer monolayers restrict it, affecting foam coarsening dynamics.

Keywords:
Atomic force microscopyBubblesColloidsInterfacesMass transferOstwald ripeningSoft matterThin films

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Area of Science:

  • Colloid and Surface Science
  • Materials Science
  • Chemical Engineering

Background:

  • Quantifying interfacial coatings' role in foam coarsening and gas transport is challenging.
  • Foam coarsening and gas transport measurements often rely on assumptions about thin film thickness.
  • Independent quantification of film thickness and interfacial permeability effects is needed.

Purpose of the Study:

  • To independently quantify the effects of interfacial coatings on gas transport dynamics.
  • To investigate how surfactant and polymer coatings differentially affect mass transfer.
  • To correlate interfacial properties with foam coarsening behavior.

Main Methods:

  • Simultaneous measurement of mass transfer between nitrogen microbubble pairs.
  • Quantification of bubble volume changes over time using microscopy.
  • Atomic Force Microscopy (AFM) to measure film thickness and mass transfer resistances.

Main Results:

  • Anionic surfactants enhance mass transfer above the critical micelle concentration.
  • Polymer monolayers at the interface restrict mass transfer.
  • Interface deformation and surface force modeling align with bubble size changes.

Conclusions:

  • Interfacial coatings significantly influence gas transport in microbubbles.
  • Anionic surfactants and polymer monolayers exhibit distinct effects on mass transfer.
  • The study provides a method for independent quantification of interfacial effects on gas transport.