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Pentacene derivative/DTTCNQ cocrystals: alkyl-confined mixed heterojunctions with molecular alignment and transport
Yudong Ma1, Yecheng Zhou2, Jianqun Jin1
1Key Laboratory for Organic Electronics and Information Displays & Jiangsu Key Laboratory for Biosensors , Institute of Advanced Materials (IAM) , Jiangsu National Synergetic Innovation Center for Advanced Materials , Nanjing University of Posts & Telecommunications , 9 Wenyuan Road , Nanjing 210023 , China . Email: iamjingzhang@njupt.edu.cn ;
Abstract:
Organic cocrystals are formed via the self-assembly of donor and acceptor constituents, which are mixed together through weak noncovalent interactions. Although they reveal unique physical features, their synthesis still faces major drawbacks for the introduction of more potential semiconductors. Herein, we first report soluble pentacene derivative (TMTES-P) based complexes, with suitable alkyl terminal groups, enabling the location of 4,8-bis(dicyanomethylene)-4,8-dihydrobenzo[1,2-b:4,5-b']-dithiophene (DTTCNQ) in the crystal lattice, thereby allowing the cocrystallization of a binary system on demand. To our surprise, via varying growth conditions, molecular disorders could be removed due to existing short-contacts as the locking force, and even the carrier charge could be changed. This organic donor-acceptor system presents unconventional insights: charge polarity control over (opto)electronic devices with a supramolecular driving force as the directional alignment guide.
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