High-performance plasmonic oblique sensors for the detection of ions

Efficient optical sensing is desirable for a wide range of applications. For sensors, the spectral factors of the sensitivity (S) and the figure of merit (FoM) and the intensity change related figure of merit (FOM^*) are all the key factors in sensing measurement. In this work, we propose and demonstrate a novel high-performance plasmonic sensor platform using a resonant cavity array grating under oblique excitation. An ultra-sharp absorption mode with a bandwidth down to 1.3 nm is achieved when the oblique angle is 7.5°. During the sensing of the Na⁺ (Cl^-) ions in the solution, the spectral S and FoM factors reach 568 nm RIU^-1 (refractive index unit) and 436 nm RIU^-1, respectively. The minimum detection limit is as low as 3.521 × 10^-6 RIU. The FOM* factor is simultaneously up to 907. Moreover, the spectral intensity change is up to 57% when only a 1% concentration change is introduced into the solution. The detection limit of the concentration of the ions can be as low as 0.002%. The sensor has great potential applications due to its ultrahigh S, FoM, and FOM^*.