Related Experiment Video
Updated: Dec 25, 2025

Probing the Structure and Dynamics of Interfacial Water with Scanning Tunneling Microscopy and Spectroscopy
Published on: May 27, 2018
Mechanical switching of current-voltage characteristics in spiropyran single-molecule junctions
Takashi Tamaki1, Keigo Minode, Yuichi Numai
1Department of Basic Science, Graduate School of Arts and Sciences, The university of Tokyo, Tokyo 153-8902, Japan. cterao@mail.ecc.u-tokyo.ac.jp.
Abstract:
The electrical properties of a single-molecule junction of spiropyran are investigated through the break junction (BJ) method, and the current-voltage (I-V) characteristics are switched from rectified to symmetric through mechanical stimulus. This phenomenon indicates isomerization from spiropyran to merocyanine. In addition, an increase in the conductance associated with isomerization is observed.
More Related Videos
Related Concept Videos
Switching of BJT
Cut-off Mode ("Off" State): In this state, both the emitter-base and collector-base junctions are...
Biasing of P-N Junction
In equilibrium, no external voltage is applied across the p-n junction. The depletion region is formed at the junction interface due to the diffusion of carriers, which leaves behind charged dopants, acceptors on the p-side, and donors on the n-side. These immobile charges create an electric field that prevents further diffusion of carriers. The related energy band...
Bipolar Junction Transistor
Biasing of Metal-Semiconductor Junctions
In Schottky junctions, where the semiconductor is n-type, applying a positive voltage to the metal relative to the semiconductor reduces its Fermi...
P-N junction
Mechanically-gated Ion Channels

