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Updated: Dec 25, 2025

Synthesis and Characterization of Functionalized Metal-organic Frameworks
Published on: September 5, 2014
General Approach for Constructing Mechanoresponsive and Redox-Active Metal-Organic and Covalent Organic Frameworks by
Xue Feng Feng1, Wen Hui Yin1, Ya Ling Fan1
1State Key Laboratory for Nuclear Resources and Environment and School of Biology, Chemistry, and Material Science, East China University of Technology, Nanchang, Jiangxi 344000, China.
Abstract:
We report for the first time the construction of mechanoresponsive and redox-active metal-organic frameworks (MOFs) and covalent organic frameworks (COFs) by anchoring ferrocene (Fc) pendants as mechanophores in the pore wall. This work outlines a simple, general, and low-cost route to tailor MOFs and COFs by a Fc unit for mechanoresponsive nature, the release of Fe ions, redox behavior, and modulation of the skeleton charge together.
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