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Multicolor 4D printing of shape-memory polymers for light-induced selective heating and remote actuation
Hoon Yeub Jeong1, Byung Hoon Woo1, Namhun Kim2
1School of Materials Science and Engineering, Ulsan National Institute of Science and Technology (UNIST), Ulsan, 44919, Republic of Korea.
Scientific Reports
|April 12, 2020
Summary
Multicolor 4D printing uses shape-memory polymers (SMPs) that change shape when exposed to specific light colors. This technology enables remote control of complex, reusable structures for diverse applications.
Area of Science:
- Materials Science
- Polymer Chemistry
- Additive Manufacturing
Background:
- Four-dimensional (4D) printing enhances three-dimensional (3D) printed objects with active, responsive functions.
- Light offers remote control for precise structural modifications in 4D printed materials.
- Shape-memory polymers (SMPs) are key materials for stimuli-responsive 4D printing applications.
Purpose of the Study:
- To demonstrate multicolor 4D printing of shape-memory polymers (SMPs).
- To achieve remote actuation of 4D printed objects using light illumination.
- To investigate the potential of multicolor SMP composites for light-induced structural changes.
Main Methods:
- Fabrication of multicolor SMP composites utilizing color-dependent selective light absorption.
- Experimental investigation of temperature changes in different colored SMPs upon light exposure.
- Development of simulations and analytical models to predict structural variations in multicolor composites.
- Demonstration of multistep actuation in a multicolor hinged structure.
Main Results:
- Distinct temperature variations were observed in different colored SMPs under light illumination.
- Simulations and calculations accurately modeled the structural changes in multicolor composites.
- Multistep actuation was successfully achieved by varying light color and illumination duration.
- The developed multicolor SMP composites exhibited efficient light-induced shape changes.
Conclusions:
- Multicolor 4D printing of SMPs enables complex geometries with predesigned, light-induced responses.
- SMPs can be reprogrammed for multiple thermal actuation cycles, enhancing reusability.
- This approach offers unique advantages for remote actuation and structural modifications.
- Multicolor 4D printing of SMPs shows significant promise for advanced structural applications and remote control.

