Over 15% Efficiency in Ternary Organic Solar Cells by Enhanced Charge Transport and Reduced Energy Loss

In this study, an efficient ternary bulk-heterojunction (BHJ) organic solar cell (OSC) is demonstrated by incorporating two acceptors, PC₆₁BM and ITC6-4F, with a polymer donor (PM6). This reveals that the addition of PC₆₁BM not only enhances the electron mobility of the derived BHJ blend but also facilitates exciton dissociation, resulting in a more balanced charge transport alongside with reduced trap-assisted charge recombination. Consequently, as compared to the pristine PM6/ITC6-4F device, the optimal ternary OSC is revealed to deliver an improved power conversion efficiency (PCE) of 15.11% with a boosted J_SC, V_OC, and fill factor (FF) simultaneously. The resultant V_OC and FF are among the highest values recorded in the literature for the ternary OSCs with a PCE exceeding 15%. This result thus suggests that besides improving the charge transport characteristics in devices, incorporating a fullerene derivative as part of the acceptor can also improve the resultant V_OC, which can reduce the energy loss to realize efficient organic photovoltaics.