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Sub kGy photon irradiation alterations in graphite.

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Polymer pencil-lead graphite (PPLG) shows potential for radiation dosimetry. Its structural and luminescence changes after X-ray and gamma irradiation correlate with absorbed radiation dose.

Keywords:
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Area of Science:

  • Materials Science
  • Radiation Physics
  • Solid State Physics

Background:

  • Polymer pencil-lead graphite (PPLG) is explored for its response to irradiation.
  • Understanding irradiation-induced structural and luminescence changes is crucial for material applications.

Purpose of the Study:

  • To analyze radiation-induced structural alterations and luminescence in PPLG.
  • To investigate the correlation between radiation dose and thermally stimulated emission.
  • To characterize the crystal structure and optical properties of irradiated PPLG.

Main Methods:

  • PPLG samples were exposed to X-ray (1-10 Gy) and gamma (30-200 Gy) irradiation.
  • Thermally stimulated emission was analyzed to estimate trapping parameters using Chen's peak-shape method.
  • X-ray diffractometry and photoluminescence spectroscopy were employed for structural and optical characterization.

Main Results:

  • Thermally stimulated emission intensity varied with PPLG diameter and radiation dose.
  • Mean atomic spacing was 0.3332 nm and degree of structural order was 26.6° for PPLG.
  • Photoluminescence spectra showed absorption at 602 nm and emission at 1074 nm, with a band gap of 1.113-1.133 eV.

Conclusions:

  • PPLG exhibits dose-dependent structural and luminescence responses to irradiation.
  • The material shows promise as a radiation dosimeter due to its sensitivity to absorbed energy.
  • Further research can optimize PPLG for specific radiation detection applications.