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Challenges to rutile-based geoscientific tools: low-temperature polymorphic TiO2 transformations and corresponding

André Jorge Pinto1, Nuria Sanchez-Pastor2, Ivan Callegari3

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This study reveals that niobium (Nb) stabilizes anatase TiO2 over rutile in hydrothermal environments, challenging traditional geochemical tools. It uncovers a rutile-to-anatase conversion pathway in Omani volcaniclastic rocks.

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Area of Science:

  • Geochemistry
  • Mineralogy
  • Petrology

Background:

  • Rutile, the stable TiO2 polymorph, is crucial for understanding geological processes.
  • Trace element composition in rutile aids in fingerprinting magmatic evolution and metamorphism.
  • Rutile-based tools are widely used in geochemistry and thermometry.

Purpose of the Study:

  • Identify TiO2 polymorphs in Omani volcaniclastic rocks.
  • Evaluate trace element contents and hydrothermal alteration effects.
  • Analyze mineral reactive pathways and textural relationships.

Main Methods:

  • Raman spectroscopy for TiO2 polymorph identification.
  • Electron Microprobe (EMP) analysis for trace element quantification.
  • Petrographic observations for textural analysis.

Main Results:

  • Interstitial TiO2 identified as anatase; rutile found as isolated grains.
  • Niobium (Nb) enrichment in anatase correlates with Nb depletion in rutile.
  • A coupled dissolution-precipitation reaction facilitates rutile-to-anatase conversion.

Conclusions:

  • Nb stabilizes anatase in lower-temperature aqueous environments.
  • Rutile likely originates from magmatic sources; anatase forms hydrothermally.
  • Findings question the universal applicability of rutile-based geochemical and thermometric tools.