Blue/red light-triggered reversible color switching based on CeO_2-x nanodots for constructing rewritable smart...

Photoreversible color switching systems (PCSSs) have attracted increasing attention in various applications, but in most PCSSs the discoloration process usually relies on harmful UV light as a stimulus and the recoloration requires high temperature. To solve these problems, we have designed and prepared CeO2-x nanodots as novel photocatalytic components in PCSSs that respond to two kinds of visible light. CeO2-x nanodots are prepared by a solvothermal reaction with l-ascorbic acid as the reducing agent. CeO2-x nanodots with a size of ∼2 nm have a high concentration of oxygen vacancies, which confers a broadened photoabsorption with an edge at 500 nm, as well as a weak photoabsorption tail in the visible region (500-800 nm). To realize the color switching, both the CeO2-x/Dye/H2O solution and CeO2-x/dye/hydroxyethyl cellulose (HEC)-coated fabrics have been prepared. Under blue (450 nm) light irradiation, both the solution and fabric show a rapid discoloration in 30 s and 150 s, respectively, due to the efficient photocatalytic reduction of the redox dye by CeO2-x. Conversely, red (630 nm) light irradiation with air confers a rapid recoloration in 35 s for the solution and 200 s for the fabric, resulting from CeO2-x-mediated self-catalyzed oxidation. In particular, the required images and letters can be remotely printed on CeO2-x/Dye/HEC-coated T-shirts with a 450 nm laser pen, and then erased with 630 nm light, with high reversibility and stability. Therefore, the present CeO2-x/Dye/HEC PCSSs have great potential to construct rewritable smart fabrics for various applications.