Related Experiment Video
Updated: Dec 22, 2025

Synthesis and Performance Evaluations of ZnCoS/ZnCdS with Twin Crystal Structure for Multifunctional Redox Photocatalysis in Energy Applications
Published on: July 25, 2025
Inter-chain double-site synergistic photocatalytic hydrogen evolution in robust cuprous coordination polymers
Ying Zang1, Jiangwei Zhang, Rui Wang
1Green Catalysis Center, and College of Chemistry, Zhengzhou University, Zhengzhou 450001, China. zangsqzg@zzu.edu.cn.
Abstract:
Here, we evaluate photocatalytic H2 generation of three stable Cu-based coordination polymers (CPs), where each two-coordinated Cu(i) is stabilized in interchain -[Cu-imidazole(R)-Cu]- units. Importantly, a record-high H2 evolution rate of 57.64 mmol g-1 h-1 is identified for Cu-MIM. Theoretical calculations reveal that the excellent catalytic performances are due to the delicate synergies of the inter-chain double-site Cu atoms.
More Related Videos
Related Concept Videos
Photochemical Electrocyclic Reactions: Stereochemistry
Selection Rules: Photochemical Activation
Reduction of Alkenes: Asymmetric Catalytic Hydrogenation
The metal catalyst used can be either heterogeneous or homogeneous. When hydrogenation of an alkene generates a chiral center, a pair of enantiomeric products is expected to form. However, an enantiomeric excess of one of the products can be facilitated using an enantioselective reaction or an...
Thermal and Photochemical Electrocyclic Reactions: Overview
Catalysis
Cycloaddition Reactions: MO Requirements for Photochemical Activation
Reduction of Benzene to Cyclohexane: Catalytic Hydrogenation

