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Catalytic Oxidation of Alcohols and Amines to Value-Added Chemicals using Water as the Solvent
Susanta Hazra1, Ekta Malik1, Abhishek Nair1
1Department of Chemistry, Indian Institute of Technology, Delhi Hauz Khas, New Delhi, 110016, India.
Abstract:
Designing reactions in aqueous media has been one of the major challenges in modern organic synthesis, especially to avoid the use of large amounts of organic solvents whose disposal is a matter of grave concern from an environmental perspective. The oxidation of alcohols and amines is an essential and important step in the synthesis of many valuable products including polymers and pharmaceuticals. In recent times, there has been a surge in the use of water as a solvent in many organic reactions. This review focuses specifically on the oxidation reactions of alcohols and amines carried out in water media using transition metal catalysts, metal-free catalysts and photocatalysts.
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